Surface ECE mechanism in protein film voltammetry—a theoretical study under conditions of square-wave voltammetry
نویسندگان
چکیده
منابع مشابه
Multistep Surface Electrode Mechanism Coupled with Preceding Chemical Reaction-Theoretical Analysis in Square-Wave Voltammetry
In this theoretical work, we present for the first time voltammetric results of a surface multistep electron transfer mechanism that is associated with a preceding chemical reaction that is linked to the first electron transfer step. The mathematical model of this so-called “surface CEE mechanism” is solved under conditions of square-wave voltammetry. We present relevant set of results portrayi...
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Square-wave voltammetry of surface redox reactions is considered as an adequate model for a protein-film voltammetric setup. Here we develop a theoretical approach to analyze the effects of temperature on square-wave voltammograms. The performed simulations address the surface redox reactions featuring slow, modest and fast electron transfer. The theoretical calculations show that the temperatu...
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ژورنال
عنوان ژورنال: Journal of Solid State Electrochemistry
سال: 2008
ISSN: 1432-8488,1433-0768
DOI: 10.1007/s10008-008-0665-5